Deadliest Catch, White Collar, and the end of The Hills

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8 p.m., FOX

MLB All-Star Game

At the 81st All-Star Game, Glee’s Amber Riley will belt out the National Anthem before baseball’s big guns pool their talents and pretend to like each other for about three hours. This year, Derek Jeter and the rest of the Yankees other American League VIPs face Albert Pujols and the National League VIPs at Angel Stadium in Anaheim.

9 p.m., DSC

Deadliest Catch

Mike and Scott duke it out for the captain chair on the Bandit as Captain Phil Harris takes a turn for the worse.

Season 2 premiere, 9 p.m., USA

White Collar

In the Season 2 premiere, Peter (Tim DeKay) and Neal (Matt Bomer) go up against a professional bank robber who sets off alarms all around the city.

Series finale, 10 p.m., MTV

The Hills

In show's last episode until, like, forever (OMG!), Kristin mulls over a big life decision, Audrina gets over her double-first-named man toy, and Lo gets serious with her boyfriend. You can also tune in at 11 p.m. for a special program featuring interviews with Lauren Conrad and the rest of the crew.

Series premiere, 10 p.m., USA

Covert Affairs

This new cop-action-drama stars Piper Perabo as CIA trainee Annie Walker and Christopher Gorham as blind military-intelligence agent Auggie Anderson. In the pilot, Annie receives a promotion to field agent—and is assigned a partner, Auggie, to help her adjust to her new responsibilities.

11:35 p.m., CBS

Late Show with David Letterman

Dave welcomes Kristin Chenoweth from Glee, Pushing Daisies, Wicked, and everything else that's awesome.

Also on the airwaves...
Losing It with Jillian, 8 p.m., NBC
Pretty Little Liars, 8 p.m., ABC Family
Downfall, 9 p.m., ABC
America's Got Talent, 9 p.m., NBC
Make It or Break It, 9 p.m., ABC Family
Warehouse 13, 9 p.m., Syfy
HawthoRNe, 9 p.m., TNT
Kathy Griffin: My Life on the D-List, 10 p.m., BRAVO
Rescue Me, 10 p.m., FX
Memphis Beat, 10 p.m., TNT
The City, Season 2 finale, 10:30 p.m., MTV
Double Exposure, 11 p.m., BRAVO
Louie, 11 p.m., FX
Cycling: Tour de France, Stage 9

What are you watching tonight?


Follow TV.com writer Stefanie Lee on Twitter: @StefAtTVDotCom