Well we have the Planners and the Executioners. For example: Planner: Marwan. Executioner: Mandy. It would be possible to list most of them in these categories.
However for me this category is an oxymoron : a contradiction in terms. There can be a worst villain and both Marwan and Mandy fit the bill as they are remorseless killers - probably psycopaths. But for "best" villain? not sure who that could be. Maybe Logan who means "well" but is a complete idiot.
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