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Sydney asks if Sam can drive the van, however she doesn't ask him if he can break into it and hotwire it.
Luckily, the door was unlocked and he finds the key above the sun visor.
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Why doesn't Sydney have any backup? Since Jack took over the mission to locate Korjev, Dixon would have been free to travel to Salzburg with Sydney, and what were Weiss and Nadia so busy with anyway?
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It doesn't seem like she activates the helicopter on purpose, it looks like it just happens to activate when she looks at it - she doesn't even touch it.
I think the baddies unleash it on her after they see her trying to tamper with it. It isn't exactly a one-use weapon so they can afford to take her down with it and still have it in working condition.
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When Sydney meets up with her contact and realizes it's a trap, she says she won't have supplies and then she and Sam run off to the Metro. Why doesn't Sydney grab what arms she can off the men she neutralized so she would at least have something? Rather than nothing.
Why doesn't Sydney have any weapons in the first place? She seems to be strangely unequipped for this mission.
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Salzburg does not have a subway system.
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Even after fully understanding the conventions and potential danger of the mini-helicopter, Sydney activates it for no good reason.
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Marshall begins giving background information on Sam Hauser to Sydney without motivation.
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In the opening scene when Sydney gets her Martini with 4 olives, she removes the olives (and puts them beside her drink), but in a following cut of the scene the olives are back in her drink.