I love this show, and I love the characters, but this is one of this episodes that shows the somewhat darker side of Clark Kent; the man who is quick to judge and a bit of a hypocrite. He is beginning to lose faith in the people who aren't his friends - or at least in the people he doesn't know - which is not helping his innate hero complex. See how he instantly doesn't believe that the people in Chloe's "group" could be innocent despite Chloe vouching for them. A younger Clark would have taken Chloe for her word and continued to search for the truth without biases. Clark getting is certainly losing his naiveté but he is also growing more cynical each episode.
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