C'mon folks this is a classic cartoon with great villains.... pure spidey, before clones, Mary Jane, black suits, symbonites, and all of the other things they do to try to make Spiderman a main stream Marvel guy.
I loved all of the fun storytelling and cheesy quips by the villains and of course Spidey himself.
As far as the pole goes, my vote would go to Green Goblin. The dual personality, the schemes, the revenge factor, knowing Peter was Spiderman....but only when the Goblin personality emerged. Doesn't get much better than that.