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It would be great if she does and have a life outside the family but it looks like she doesn't want any.
Usually it depends. Some episodes have her being friends with the other moms or wives, other times she has no friends at all.
Watch Scenes from the Class Struggle in Springfield. She gained some friends in that episode.
SHe does host parties and gatherings for other parents with infants, but it has never been explored as much.
Oh, there was her old college buddy that Lisa got attached too.
The recent episode when she was hanging out with the cool moms but dropped out when one of the cool moms said that Bart is a bad apple (which is true). Marge deserves to have friends.
I saw that episode and it is true. I wished all the wives had friends.
Refer to season 5 episode 6 `Marge on the Lam` for the reason why she has no friends.